{"id":11831,"date":"2020-07-01T09:50:10","date_gmt":"2020-07-01T01:50:10","guid":{"rendered":"http:\/\/www.ace-pow.com\/?p=11831"},"modified":"2023-01-10T09:56:54","modified_gmt":"2023-01-10T01:56:54","slug":"%e6%b0%b4%e7%b3%bb%e7%94%b5%e6%b1%a0%e5%ae%b9%e9%87%8f%e8%a1%b0%e5%87%8f%e6%9c%ba%e7%90%86","status":"publish","type":"post","link":"http:\/\/www.ace-pow.com\/sxdc-rlsj","title":{"rendered":"\u6c34\u7cfb\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\u673a\u7406"},"content":{"rendered":"\n

\u9502\u79bb\u5b50\u5d4c\u5165\u5316\u5408\u7269\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u5316\u5b66\/\u7535\u5316\u5b66\u53cd\u5e94\u6bd4\u5728\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u8981\u590d\u6742\u5f97\u591a\uff1a\u8981\u6d89\u53ca\u5230\u8bb8\u591a\u526f\u53cd\u5e94\uff0c\u4f8b\u5982\u7535\u6781\u6750\u6599\u4e0e\u6c34\u548c\u6c27\u6c14\u7684\u53cd\u5e94;\u7535\u6781\u6750\u6599\u5d4c\u9502\u8fc7\u7a0b\u4e2d\u7684\u8d28\u5b50\u534f\u540c\u5d4c\u5165;\u6c27\u6c14\u548c\u6c22\u6c14\u7684\u6790\u51fa;\u7535\u6781\u6750\u6599\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u3002<\/span><\/p>\n\n\n

\n
\"\u6c34\u7cfb\u7535\u6c60\"<\/figure><\/div>\n\n\n

<\/span><\/p>\n\n\n\n

\u5df2\u7ecf\u8bc1\u5b9e\u5f53\u76f8\u5bf9\u4e0eLi\/Li+\u7684\u7535\u4f4d\u9ad8\u4e8e3.3V\u65f6\uff0c\u7535\u6781\u6750\u6599\u5728\u7a7a\u6c14\u4e2d\u57fa\u672c\u4e0a\u662f\u7a33\u5b9a\u7684\u3002\u800c\u5bf9\u4e8e\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\uff0c\u5d4c\u5165\u7535\u4f4d\u901a\u5e38\u4f4e\u4e8e3.3V\u3002<\/span><\/p>\n\n\n\n

\u9996\u5148\u6211\u4eec\u8981\u8003\u8651\u7535\u6781\u6750\u6599\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u6c34\u7cfb\u7535\u6c60\u901a\u5e38\u662f\u655e\u5f00\u4e8e\u7a7a\u6c14\u4e2d\uff0c\u6211\u4eec\u9700\u8981\u8003\u8651\u7535\u6781\u6750\u6599\u5728\u6c34\u548c\u6c27\u6c14\u90fd\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u7684\u7a33\u5b9a\u6027\u3002\u3002<\/span><\/p>\n\n\n\n

\u82e5\u5728\u6c34\u548c\u6c27\u6c14\u90fd\u5b58\u5728\u65f6\uff0c\u4ee5\u4e0b\u53cd\u5e94\u5c06\u4f1a\u53d1\u751f\uff1a<\/span><\/p>\n\n\n\n

Li(fimtercalated)+(1\/4)O2 +(1\/2)H20 \u2192Li++HO-<\/span><\/p>\n\n\n\n

\u5d4c\u9502\u5316\u5408\u7269\u4e8e\u6c34\u548c\u6c27\u6c14\u8fbe\u5230\u5e73\u8861\u65f6\u8ba1\u7b97\u5f97\u5230\u7684\u7684\u5e73\u8861\u7535\u4f4dV(x)= 4.27 -0.059pH(V)<\/span><\/p>\n\n\n\n

\u5728\u6c27\u6c14\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0c\u6ca1\u6709\u6750\u6599\u53ef\u4ee5\u7528\u6765\u4f5c\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u3002\u8fd9\u662f\u56e0\u4e3a\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u7684\u9502\u79bb\u5b50\u5d4c\u5165\u7535\u4f4d\u4e00\u822c\u76f8\u5bf9\u4e8eLi\/Li+\u4f4e\u4e8e3.0V\uff0c\u800c\u8ba1\u7b97\u5f97\u5230\u7684\u5e73\u8861\u7535\u4f4d\u5728PH\u4e3a7\u65f6\u662f3.85V\uff0c\u5728PH\u4e3a13\u65f6\u662f3.5V\u3002\u8fd9\u8868\u660e\u6240\u6709\u8d1f\u6781\u6750\u6599\u7684\u8fd8\u539f\u6001\u7406\u8bba\u4e0a\u5c06\u4f1a\u88ab\u6c34\u548c\u6c27\u6c14\u6c27\u5316\uff0c\u800c\u4e0d\u662f\u8fdb\u884c\u7535\u5316\u5b66\u6c27\u5316\u53cd\u5e94\u3002\u6211\u4eec\u8ba4\u4e3a\u5728\u6c27\u6c14\u5b58\u5728\u65f6\uff0c\u9002\u5408\u4f5c\u4e3a\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u4efb\u4f55\u6750\u6599\u5728\u653e\u7535\u6001\u90fd\u4f1a\u548c\u6c27\u6c14\u548c\u6c34\u53cd\u5e94\uff0c\u8fd9\u662f\u5bfc\u81f4\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\u7684\u539f\u56e0\u3002<\/span><\/p>\n\n\n\n

\u5728\u65e0\u6c27\u7684\u60c5\u51b5\u4e0b\uff0c\u5d4c\u9502\u5316\u5408\u7269\u5c06\u4f1a\u4e8e\u6c34\u53d1\u751f\u5982\u4e0b\u53cd\u5e94\uff1a<\/span><\/p>\n\n\n\n

Li(tintercalated)+H20\u2192Li++OH-+(1\/2)H2<\/span><\/p>\n\n\n\n

\u5d4c\u9502\u5316\u5408\u7269\u4e8e\u6c34\u8fbe\u5230\u5e73\u8861\u65f6\u8ba1\u7b97\u5f97\u5230\u7684\u7684\u5e73\u8861\u7535\u4f4d\u662f\uff1a<\/span><\/p>\n\n\n\n

V(x)=3.04-0.059pH(V)<\/span><\/p>\n\n\n\n

\u901a\u8fc7\u5e7f\u6cdb\u7814\u7a76\u7535\u6781\u6750\u6599\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\uff0c\u4f34\u968f\u7740\u9502\u79bb\u5b50\u5d4c\u5165\u7684\u8d28\u5b50\u5d4c\u5165\uff0c\u6c27\u6c14\u548c\u6c22\u6c14\u7684\u6790\u51fa\u53cd\u5e94\uff0c\u548c\u7535\u6781\u6750\u6599\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u6027\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff1a\u5728\u6c27\u6c14\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0c\u9002\u5408\u4f5c\u4e3a\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u4efb\u4f55\u6750\u6599\u5728\u653e\u7535\u6001\u90fd\u4f1a\u548c\u6c27\u6c14\u548c\u6c34\u53cd\u5e94\uff0c\u8fd9\u662f\u5bfc\u81f4\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\u7684\u539f\u56e0\u3002\u901a\u8fc7\u5bc6\u5c01\u7535\u6c60\u9664\u6c27\uff0c\u8c03\u6574\u7535\u89e3\u6db2\u7684pH\u503c\uff0c\u4f7f\u7528\u70ad\u5305\u8986\u7684\u7535\u6781\u6750\u6599\uff0c\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u53ef\u4ee5\u5177\u6709\u975e\u5e38\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

\u9502\u79bb\u5b50\u5d4c\u5165\u5316\u5408\u7269\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u5316\u5b66\/\u7535\u5316\u5b66\u53cd\u5e94\u6bd4\u5728\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u8981\u590d\u6742\u5f97\u591a\uff1a\u8981\u6d89\u53ca\u5230\u8bb8\u591a\u526f\u53cd\u5e94\uff0c\u4f8b\u5982\u7535\u6781\u6750\u6599\u4e0e\u6c34\u548c\u6c27\u6c14\u7684\u53cd\u5e94;\u7535\u6781\u6750\u6599\u5d4c\u9502\u8fc7\u7a0b\u4e2d\u7684\u8d28\u5b50\u534f\u540c\u5d4c\u5165;\u6c27\u6c14\u548c\u6c22\u6c14\u7684\u6790\u51fa;\u7535\u6781\u6750\u6599\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u3002 \u5df2\u7ecf\u8bc1\u5b9e\u5f53\u76f8\u5bf9\u4e0eLi\/Li+\u7684\u7535\u4f4d\u9ad8\u4e8e3.3V\u65f6\uff0c\u7535\u6781\u6750\u6599\u5728\u7a7a\u6c14\u4e2d\u57fa\u672c\u4e0a\u662f\u7a33\u5b9a\u7684\u3002\u800c\u5bf9\u4e8e\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\uff0c\u5d4c\u5165\u7535\u4f4d\u901a\u5e38\u4f4e\u4e8e3.3V\u3002 \u9996\u5148\u6211\u4eec\u8981\u8003\u8651\u7535\u6781\u6750\u6599\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u6c34\u7cfb\u7535\u6c60\u901a\u5e38\u662f\u655e\u5f00\u4e8e\u7a7a\u6c14\u4e2d\uff0c\u6211\u4eec\u9700\u8981\u8003\u8651\u7535\u6781\u6750\u6599\u5728\u6c34\u548c\u6c27\u6c14\u90fd\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u7684\u7a33\u5b9a\u6027\u3002\u3002 \u82e5\u5728\u6c34\u548c\u6c27\u6c14\u90fd\u5b58\u5728\u65f6\uff0c\u4ee5\u4e0b\u53cd\u5e94\u5c06\u4f1a\u53d1\u751f\uff1a Li(fimtercalated)+(1\/4)O2 +(1\/2)H20 \u2192Li++HO- \u5d4c\u9502\u5316\u5408\u7269\u4e8e\u6c34\u548c\u6c27\u6c14\u8fbe\u5230\u5e73\u8861\u65f6\u8ba1\u7b97\u5f97\u5230\u7684\u7684\u5e73\u8861\u7535\u4f4dV(x)= 4.27 -0.059pH(V) \u5728\u6c27\u6c14\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0c\u6ca1\u6709\u6750\u6599\u53ef\u4ee5\u7528\u6765\u4f5c\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u3002\u8fd9\u662f\u56e0\u4e3a\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u7684\u9502\u79bb\u5b50\u5d4c\u5165\u7535\u4f4d\u4e00\u822c\u76f8\u5bf9\u4e8eLi\/Li+\u4f4e\u4e8e3.0V\uff0c\u800c\u8ba1\u7b97\u5f97\u5230\u7684\u5e73\u8861\u7535\u4f4d\u5728PH\u4e3a7\u65f6\u662f3.85V\uff0c\u5728PH\u4e3a13\u65f6\u662f3.5V\u3002\u8fd9\u8868\u660e\u6240\u6709\u8d1f\u6781\u6750\u6599\u7684\u8fd8\u539f\u6001\u7406\u8bba\u4e0a\u5c06\u4f1a\u88ab\u6c34\u548c\u6c27\u6c14\u6c27\u5316\uff0c\u800c\u4e0d\u662f\u8fdb\u884c\u7535\u5316\u5b66\u6c27\u5316\u53cd\u5e94\u3002\u6211\u4eec\u8ba4\u4e3a\u5728\u6c27\u6c14\u5b58\u5728\u65f6\uff0c\u9002\u5408\u4f5c\u4e3a\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u4efb\u4f55\u6750\u6599\u5728\u653e\u7535\u6001\u90fd\u4f1a\u548c\u6c27\u6c14\u548c\u6c34\u53cd\u5e94\uff0c\u8fd9\u662f\u5bfc\u81f4\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\u7684\u539f\u56e0\u3002 \u5728\u65e0\u6c27\u7684\u60c5\u51b5\u4e0b\uff0c\u5d4c\u9502\u5316\u5408\u7269\u5c06\u4f1a\u4e8e\u6c34\u53d1\u751f\u5982\u4e0b\u53cd\u5e94\uff1a Li(tintercalated)+H20\u2192Li++OH-+(1\/2)H2 \u5d4c\u9502\u5316\u5408\u7269\u4e8e\u6c34\u8fbe\u5230\u5e73\u8861\u65f6\u8ba1\u7b97\u5f97\u5230\u7684\u7684\u5e73\u8861\u7535\u4f4d\u662f\uff1a V(x)=3.04-0.059pH(V) \u901a\u8fc7\u5e7f\u6cdb\u7814\u7a76\u7535\u6781\u6750\u6599\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\uff0c\u4f34\u968f\u7740\u9502\u79bb\u5b50\u5d4c\u5165\u7684\u8d28\u5b50\u5d4c\u5165\uff0c\u6c27\u6c14\u548c\u6c22\u6c14 […]<\/p>\n","protected":false},"author":3720,"featured_media":11832,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[24],"tags":[],"_links":{"self":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/11831"}],"collection":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/users\/3720"}],"replies":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/comments?post=11831"}],"version-history":[{"count":4,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/11831\/revisions"}],"predecessor-version":[{"id":19848,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/11831\/revisions\/19848"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/media\/11832"}],"wp:attachment":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/media?parent=11831"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/categories?post=11831"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/tags?post=11831"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}